The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Aromatic compounds / Aromatic radicals / C6H5 / Wallington(1998)_295K_250nm

DATAFILE: C6H5_Wallington(1998)_295K_250nm.txt
NAME: phenyl radical
FORMULA: C6H5
AUTHOR(YEAR): Wallington(1998)
T: 295K
λ: 250nm
BIBLIOGRAPHY: T.J. Wallington, H. Egsgaard, O.J. Nielsen, J. Platz, J. Sehested, and T. Stein, "UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase", Chem. Phys. Lett. 290, 363-370 (1998); DOI: 10.1016/S0009-2614(98)00537-5
COMMENTS: Pulse radiolysis transient UV-visible absorption spectroscopy was used to study the UV-visible absorption spectrum (225-575 nm) of the phenyl radical

The phenyl radical spectrum was measured relative to that of nitrosobenzene, and based upon σ(C6H5NO)270 nm = 3.82×10-17 cm2 molecule-1 an absorption crosssection for the phenyl radical at 250 nm was derived

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